Power Supply Connectors and Pinouts - modDIY.comExplore further
The new 24 pin connector added one line apiece for ground, 3.3, 5, and 12 volts. The extra pins made the auxiliary power cable unnecessary so most ATX12V 2.x power supplies don't have them. The 24 pin connector is polarized so it can only be plugged in pointing in the correct direction. Pinout.
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